Mathematical Foundation of Quantum Mechanics

This is abrief introduction to the mathematical foundations of quan- tum mechanics based on lectures given by the author to Ph.D.students at the Delhi Centre of the Indian Statistical Institute during the years 1980- 1985 in order to initiate active research in the emerging field of quantum prob ability.

The German edition of this book appeared in 1932 under the title "Die gruppentheoretische Methode in der Quantenmechanik". Its aim was, to explain the fundamental notions of the Theory of Groups and their Representations, and the application of this theory to the Quantum Mechanics of Atoms and Molecules. The book was mainly written for the benefit of physicists who were supposed to be familiar with Quantum Mechanics. However, it turned out that it was also used by. mathematicians who wanted to learn Quantum Mechanics from it. Naturally, the physical parts were too difficult for mathematicians, whereas the mathematical parts were sometimes too difficult for physicists. The German language created an additional difficulty for many readers. In order to make the book more readable for physicists and mathe­ maticians alike, I have rewritten the whole volume. The changes are most notable in Chapters 1 and 6. In Chapter t, I have tried to give a mathematically rigorous exposition of the principles of Quantum Mechanics. This was possible because recent investigations in the theory of self-adjoint linear operators have made the mathematical foundation of Quantum Mechanics much clearer than it was in t 932. Chapter 6, on Molecule Spectra, was too much condensed in the German edition. I hope it is now easier to understand. In Chapter 2-5 too, numerous changes were made in order to make the book more readable and more useful.

The German edition of this book appeared in 1932 under the title "Die gruppentheoretische Methode in der Quantenmechanik". Its aim was, to explain the fundamental notions of the Theory of Groups and their Representations, and the application of this theory to the Quantum Mechanics of Atoms and Molecules. The book was mainly written for the benefit of physicists who were supposed to be familiar with Quantum Mechanics. However, it turned out that it was also used by. mathematicians who wanted to learn Quantum Mechanics from it. Naturally, the physical parts were too difficult for mathematicians, whereas the mathematical parts were sometimes too difficult for physicists. The German language created an additional difficulty for many readers. In order to make the book more readable for physicists and mathe­ maticians alike, I have rewritten the whole volume. The changes are most notable in Chapters 1 and 6. In Chapter t, I have tried to give a mathematically rigorous exposition of the principles of Quantum Mechanics. This was possible because recent investigations in the theory of self-adjoint linear operators have made the mathematical foundation of Quantum Mechanics much clearer than it was in t 932. Chapter 6, on Molecule Spectra, was too much condensed in the German edition. I hope it is now easier to understand. In Chapter 2-5 too, numerous changes were made in order to make the book more readable and more useful.

I am very happy to accept the translators' invitation to write a few lines of introduction to this book. Of course, there is little need to explain the author. Pauli's first famous work, his article on the theory of relativity in the Encyklopädie der Mathematischen Wissenschaften was written at the age of twenty. He afterwards took part in the development of atomic physics from the still essentially classical picture of Bohr's early work to the true quantum mechanics. Thereafter, some of his work concerned the treatment of problems in the framework of the new theory, especially his paper on the hydrogen atom following the matrix method without recourse to Schrodinger's analytic form of the theory. His greatest achievement, the exclusion principle, generally known today under his own name as the Pauli principle, that governs the quantum theory of all problems including more than one electron, preceded the basic work of Heisenberg and Schrodinger, and brought him the Nobel prize. It includes the mathematical treatment of the spin by means of the now so well­ known Pauli matrices. In 1929, in a paper with Heisenberg, he laid the foundation of quantum electrodynamics and, in doing so, to the whole theory of quantized wave fields which was to become the via regia of access to elementary particle physics, since here for the first time processes of generation and annihilation of particles could be described for the case of the photons.

I am very happy to accept the translators' invitation to write a few lines of introduction to this book. Of course, there is little need to explain the author. Pauli's first famous work, his article on the theory of relativity in the Encyklopädie der Mathematischen Wissenschaften was written at the age of twenty. He afterwards took part in the development of atomic physics from the still essentially classical picture of Bohr's early work to the true quantum mechanics. Thereafter, some of his work concerned the treatment of problems in the framework of the new theory, especially his paper on the hydrogen atom following the matrix method without recourse to Schrodinger's analytic form of the theory. His greatest achievement, the exclusion principle, generally known today under his own name as the Pauli principle, that governs the quantum theory of all problems including more than one electron, preceded the basic work of Heisenberg and Schrodinger, and brought him the Nobel prize. It includes the mathematical treatment of the spin by means of the now so well­ known Pauli matrices. In 1929, in a paper with Heisenberg, he laid the foundation of quantum electrodynamics and, in doing so, to the whole theory of quantized wave fields which was to become the via regia of access to elementary particle physics, since here for the first time processes of generation and annihilation of particles could be described for the case of the photons.