Mechanical Properties of Solid Polymers

by Joel R. Fried (Author)

The goal of this monograph is to summarize the different quantum­ mechanical methods developed in the last 20 years to treat the electronic structure of polymers. Owing to the nature of the problem, these methods consist of a mixture of quantum-chemical and solid-state physical tech­ niques. The theory described in Part I treats, besides the Hartree-Fock problem, the· electron correlation, and it has also been developed for disordered polymeric systems. Though for obvious reasons the book could not include all the existing calculations, each new method des­ cribed is illustrated by a few applications, with a discussion of the numerical results obtained. Far more details see the Introduction to Part I. The second part contains the theoretical calculation of different properties of polymers based on the methods systematically introduced in the first part. The properties calculated include the electronic and vibrational spectra of polymers, and the computation of their transport, magnetic, and mechanical properties. In cases where reliable ex­ perimental data are available, the theoretical results are compared with them.

This two-volume set covers current knowledge on all aspects of polyester synthesis, structure, properties (chemical, physical and application relevant) and recycling. The most important technical polyesters are presented in detailed chapters, homogeneous polymers as well as copolymers, blends and high-performance reinforced polyester materials are discussed. Handbook of Thermoplastic Polyesters is directed towards chemists, physicists and engineers working in research, development and application of polymers.

The applications of ionic liquids can be enormously expanded by arranging the organic ions in the form of a polymer architecture.

by Andreea Irina Barzic (Editor), Silvia Ioan (Editor)