Quantum Theory

"Dr. Gamow, physicist and gifted writer, has sketched an intriguing portrait of the scientists and clashing ideas that made the quantum revolution." — Christian Science Monitor

These are the proceedings of the Conference on Coding Theory, Cryptography, and Number Theory held at the U. S. Naval Academy during October 25-26, 1998. This book concerns elementary and advanced aspects of coding theory and cryptography. The coding theory contributions deal mostly with algebraic coding theory. Some of these papers are expository, whereas others are the result of original research. The emphasis is on geometric Goppa codes (Shokrollahi, Shokranian-Joyner), but there is also a paper on codes arising from combinatorial constructions (Michael). There are both, historical and mathematical papers on cryptography. Several of the contributions on cryptography describe the work done by the British and their allies during World War II to crack the German and Japanese ciphers (Hamer, Hilton, Tutte, Weierud, Urling). Some mathematical aspects of the Enigma rotor machine (Sherman) and more recent research on quantum cryptography (Lomonoco) are described. There are two papers concerned with the RSA cryptosystem and related number-theoretic issues (Wardlaw, Cosgrave).

An appreciable part of the scientific community seems to believe that contemporary physical theories are likely to affect the construction of any overall philosophical outlook, especially insofar as they are relevant to the settlement of certain persistent philosophical controversies. Two physical conceptions - the theory of relativity and the quantum theory - which have brought about a reformulation of the fundamental principles common to all the natural sciences, are considered particularly important in this regard. These conceptions have shed new light, it is held, on a number of problems involving empiricism and rationalism, determinism and indeterminism, materialism and spiritualism, idealism and realism. Such philosophical implications of the theory of relativity and quantum theory have been Widely discussed by both philosophers and philosophizing physicists. The trend in this development has been to portray these theories as generally conducive to an idealist stance.

The present text is a rational analysis of the concept of the chemical bond by means of the principles of wave mechanics. The discussion of the material has been arranged so as to render its main content comprehensible for readers who may not have had pre"ious training in quantum mechanics. The text comprises three major parts. It begins with an exposition of the fundamental ideas. In this section the principles are reviewed from which de Broglie developed his mechanics; this allows the book to be read by chemistry majors and freshmen alike. However, we believe that it may also be of interest to university-and college teachers who must include certain aspects of quantum chemistry into their courses while being insufficiently familiar with the subject. It may even be of interest to science teachers in secondary schools. Finally, having been a witness to the evolution of these notions for over a quarter of a century, we present certain concepts from a particular point of view which might prove attractive to chemists of all kinds, perhaps even quantum chemists. The second, more technical part summarizes the methods of constructing wave functions that describe the electrons in molecules. This section can only be fully appreciated by those readers who are familiar with some aspects of the algorithms used in quantum mechanics.

The present text is a rational analysis of the concept of the chemical bond by means of the principles of wave mechanics. The discussion of the material has been arranged so as to render its main content comprehensible for readers who may not have had pre"ious training in quantum mechanics. The text comprises three major parts. It begins with an exposition of the fundamental ideas. In this section the principles are reviewed from which de Broglie developed his mechanics; this allows the book to be read by chemistry majors and freshmen alike. However, we believe that it may also be of interest to university-and college teachers who must include certain aspects of quantum chemistry into their courses while being insufficiently familiar with the subject. It may even be of interest to science teachers in secondary schools. Finally, having been a witness to the evolution of these notions for over a quarter of a century, we present certain concepts from a particular point of view which might prove attractive to chemists of all kinds, perhaps even quantum chemists. The second, more technical part summarizes the methods of constructing wave functions that describe the electrons in molecules. This section can only be fully appreciated by those readers who are familiar with some aspects of the algorithms used in quantum mechanics.

In a complex field, this work is a first. The authors make an important connection between the conduction electrons and the Fermi surface in an elementary manner in the text. No currently available text explains this connection. They do this by deriving Newtonian equations of motion for the Bloch electron and diagonalizing the inverse mass (symmetric) tensor. The authors plan to follow up this book with a second, more advanced book on superconductivity and the Quantum Hall Effect.