Chemistry of Carbon Dioxide

Transformation and Utilization of Carbon Dioxide shows the various organic, polymeric and inorganic compounds which result from the transformation of carbon dioxide through chemical, photocatalytic, electrochemical, inorganic and biological processes.

by Paul J. Karol (Author)
Covers the truly varied roles carbon dioxide has played and continues to play in the character of our planet

by Jinli Qiao (Editor), Yuyu Liu (Editor), Jiujun Zhang (Editor)

This book covers the latest technology and experimental scientific advancements in converting carbon dioxide (CO2) from waste to useful commercial products. This approach helps to mitigate climate change due to carbon emission greenhouse effect and also create a circular economy through CO2 waste capture and utilization to produce CO2 derived products. This provides new direction for government organizations, manufacturing industries (fuel, chemicals, building materials) and investment firms to work towards a zero carbon future. This book caters to researchers, policymakers, industrial practitioners who are interested in more sustainable practices in carbon dioxide technology.

In this volume, Professor He and his coworkers summarize polyethylene glycol (PEG)-promoted CO2 chemistry on the basis of understanding about phase behavior of PEG/CO2 system and reaction mechanism at molecular level. As PEG could be utilized as a green replacement for organic solvents, phase-transfer catalyst, surfactant, support in various reaction systems, significantly promoting catalytic activity and recovering expensive metal catalysts, particularly regarded as a CO2-philic material, the authors focus on special applications of PEG in CO2 capture and utilization, including PEG-functionalized catalysts for efficient transformation of CO2 and PEG-functionalized absorbents for efficient CO2 capture.

This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively.