Theoretical Physics 5 Thermodynamics

Der Grundkurs Theoretische Physik deckt in 7 Bänden alle für das Diplom und für Bachelor/Master-Studiengänge maßgeblichen Gebiete ab. Jeder Band vermittelt das im jeweiligen Semester notwendige theoretisch-physikalische Rüstzeug.

Der Grundkurs Theoretische Physik deckt in 7 Bänden alle für das Diplom und für Bachelor/Master-Studiengänge maßgeblichen Gebiete ab. Jeder Band vermittelt das im jeweiligen Semester notwendige theoretisch-physikalische Rüstzeug. Übungsaufgaben mit ausführlichen Lösungen dienen der Vertiefung des Stoffs.

This introductory text treats thermodynamics as an incomplete description of quantum systems with many degrees of freedom. Its main goal is to show that the approach to equilibrium—with equilibrium characterized by maximum ignorance about the open system of interest—neither requires that many particles nor is the precise way of partitioning, relevant for the salient features of equilibrium and equilibration. Furthermore, the text depicts that it is indeed quantum effects that are at work in bringing about thermodynamic behavior of modest-sized open systems, thus making Von Neumann’s concept of entropy appear much more widely useful than sometimes feared, far beyond truly macroscopic systems in equilibrium.

This book is a primary survey of basic thermodynamic concepts that will allow one to predict states of a fuel cell system, including potential, temperature, pressure, volume and moles. The specific topics explored include enthalpy, entropy, specific heat, Gibbs free energy, net output voltage irreversible losses in fuel cells and fuel cell efficiency.