Fuel Cells

This textbook covers essential electrochemistry and materials science content and provides an extensive collection of examples in order to bridge the gap between engineering students’ basic knowledge and the concrete skills they need to handle practical problems in fuel cells. The book starts with an introduction to the basic thermodynamics and electrochemistry principles and techniques in fuel cells. It subsequently discusses fuel cell operation principles, electrocatalysts, electrode materials, cell and system configuration and technologies in low-temperature fuel cells such as alkaline fuel cells and proton exchange membrane fuel cells, and in high-temperature fuel cells including solid oxide and molten carbonate fuel cells. Other energy conversion and storage technologies such as supercapacitors, batteries and electrolysis are also covered.

This book comprehensively reviews the key topics in microbial fuel cells (MFC) and its applications in areas related to energy and environmental mitigation. It covers the microbial electrochemistry and the generation of electricity from waste, various synthesis and characterization approaches of polymer-based MFC electrodes, the multifunctional properties of a MFC which allows its simultaneous use as a fuel cell, bioremediation and biosensor device. It provides new direction to the readers to better understand the chemistry in MFC and methods to improve their desired properties. This book is a very valuable reference source for graduates and postgraduates, engineers and research scholars in the areas related to fuel cells electrochemistry and pollution mitigation.

This book is a comprehensive review of high-temperature polymer electrolyte membrane fuel cells (PEMFCs). PEMFCs are the preferred fuel cells for a variety of applications such as automobiles, cogeneration of heat and power units, emergency power and portable electronics. The first 5 chapters of the book describe rationalization and illustration of approaches to high temperature PEM systems. Chapters 6 - 13 are devoted to fabrication, optimization and characterization of phosphoric acid-doped polybenzimidazole membranes, the very first electrolyte system that has demonstrated the concept of and motivated extensive research activity in the field. The last 11 chapters summarize the state-of-the-art of technological development of high temperature-PEMFCs based on acid doped PBI membranes including catalysts, electrodes, MEAs, bipolar plates, modelling, stacking, diagnostics and applications.

As the world accelerates towards a renewable energy transition, the demand for critical raw materials (CRMs) for energy generation, conversion, and storage technologies is seeing a drastic increase. Such materials are not only subject to limited supply and extreme price volatility but can also represent serious burdens to the environment, to human health, and also to socio-political systems.

This book reports on the most recent applications of processes with a particular focus on the source and the properties of biogas and on the characteristics of the fuel cells (FCs). It describes adsorbing materials of potential interest are reviewed and the preparation methods and treatments employed to improve the adsorption properties as well as the stability and regenerability. The characterization of the chemical and physical properties involved in these processes is examined in particular detail. The book also covers aspects that concern the development of the adsorption apparatus with particular attention on the target of low residual concentration and high selectivity.

The book starts with a theoretical understanding of electrocatalysis in the framework of density functional theory followed by a vivid review of oxygen reduction reactions.